Dozens of exhausted pro-democracy protesters barricaded inside a Hong Kong university defied warnings Tuesday to surrender, as a police siege of the campus dragged into a third day. High school students were among those holed up inside the battered Hong Kong Polytechnic University (PolyU), fearing arrest or being shot by police, with many huddled in silver emergency survival blankets to keep themselves warm. Some protesters escaped overnight by slithering down ropes from a footbridge to a road below, where they were whisked away on motorbikes, while others disappeared into manholes. In an apparently coordinated effort to distract police during the escape operation, tens of thousands of people streamed towards the PolyU campus as clashes raged with police in the nearby Kowloon district. The stand-off is the most intense and prolonged of Hong Kong's pro-democracy crisis, which has seen millions take to the streets since June to voice anger at China eroding the territory's freedoms. A new phase of mass disruption last week caused chaos throughout the international financial hub, with schools closed, train lines disrupted and major roads blocked by barricades. The move by hundreds of hardcore protesters to take over PolyU at the weekend was also a new tactic. Previously they had focused on flash protests and acts of vandalism. The siege at PolyU had seen the demonstrators repelling police surges with a barrage of Molotov cocktails, arrows and bricks. They also set fire to the university entrance on Monday. After one officer near the campus was shot in the leg by an arrow, which had apparently been fired from one of the university archery kits, police warned they were prepared to use live rounds. Footage on Monday showed armoured police beating fallen protesters with batons as they lay on the ground. One officer was filmed stamping on the head of a man who was already subdued. Alleged police brutality is one of the central complaints of the protest movement, but senior officers say their colleagues are acting in accordance with the law. In her first public comments on the PolyU crisis, Hong Kong Chief Executive Carrie Lam on Tuesday morning said the remaining protesters must surrender if there was to be a peaceful ending. "This objective could only be achieved with the full cooperation of the protesters, including of course the rioters that they have to stop violence, give up the weapons and come out peacefully and take the instructions from the police," Ms Lam said. Ms Lam said children who surrendered would not be arrested, though protesters over the age of 18 would face charges of rioting. But, with police custody their best option, some those who remained inside voiced determination to remain. "Even if we surrender they will still put us to jail. It seems we have two options, but actually we only have one... which is jail", one of the protesters, a mechanical engineering student who gave his name as Matthew, said inside the campus. Ms Lam said about 100 people remained inside on Tuesday morning. With the crisis deepening, China's ambassador to Britain upped the ante on Monday. "The Hong Kong government is trying very hard to put the situation under control," Liu Xiaoming said. "If the situation becomes uncontrollable, the central government would certainly not sit on our hands and watch. We have enough resolution and power to end the unrest." In another ominous signal, China insisted it had sole authority to rule on constitutional matters in Hong Kong. The warning came as it condemned a decision by the city's high court on Monday to overturn a ban on face masks worn by pro-democracy protesters. Only China's parliament has the right to rule on Hong Kong's Basic Law - the city's constitution, Zang Tiewei, a spokesman for the body, said in comments carried by state-run media. "No other institution has the right to make judgments or decisions," Mr Zang said, according to a state media report posted on the parliament's website.